Seminars Archive

Precision measurements in few-electron molecules

Abstract
Few-electron molecules are attractive systems for precision spectroscopy because their properties can be calculated with high accuracy by quantum-chemical methods.1,2,3 The measurements serve to test theoretical predictions, ideally at the level where their accuracy is limited by the uncertainties of the fundamental constants or by unrecognized physical effects. I will report on precision measurements of energy intervals in cold samples of H2 and metastable He2. In the case of H2, we determine the ionization energy with a precision (Δν/ν) of 10-10 from high-resolution Rydberg spectra4,5 and derive the dissociation energy with an accuracy of 350 kHz, approaching the level where the size of the proton and the uncertainty in the proton-to-electron mass ratio would limit the accuracy of otherwise exact calculations. Comparison will be made to recent theoretical results in the context of a more-than-100-year-long series of experimental and theoretical determinations of the dissociation energy of H2. In the case of the He2, we use multistage Zeeman deceleration to prepare slow, cold metastable molecules in selected spin-rotational components of the metastable a state. We exploit the long transit times of these molecules through microwave and laser fields to measure fine-structure intervals in the a state, the Rydberg spectrum of He2, and the energy-level structure of He2+.6 1. V. I. Korobov, L. Hilico and J.-P. Karr, Phys. Rev. Lett. 118, 233001 (2017). 2. M. Puchalski, A. Spyszkiewicz, J. Komasa and K. Pachucki, Phys. Rev. Lett. 121, 073001 (2018) 3. E. Mátyus, J. Chem. Phys. 149, 194112 (2018) 4. M. Beyer, N. Hölsch, J. A. Agner, J. Deiglmayr, H. Schmutz and F. Merkt, Phys. Rev. A 97, 012501 (2018) 5. C.-F. Cheng et al., Phys. Rev. Lett. 121, 013001 (2018) 6. P. Jansen, L. Semeria and F. Merkt, Phys. Rev. Lett. 120, 043001 (2018); J. Chem. Phys. 149, 154302 (2018)