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Gas Phase highlights
Elucitading the 3d electronic configuration in MgPc
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To shed light on the metal 3d electronic structure of manganese phthalocyanine we performed photoelectron measurements both in the gas phase and as thin film. J. Bramboiu et al. JPCA (2014).
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VB electronic structure of fePc: an experimental and theoretical PE study
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A Variable Energy Photon Electron Spectroscopic study of FePc has been perfomed and compared with state-of-art DFT calculations.
B. Brena et al. J. Chem. Phys. (2011)
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sp hybridization in free carbon nanoparticles - presence and stability observed by NEXAFS
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The presence and stability of sp hybridized atoms in free carbon nanoparticles was investigated by NEXAFS spectroscopy. L. Ravagnan et al. Chem. Comm. (2011)
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VPEPES of tris-cyclopentadienyl lanthanides
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The gas phase photoelectron (PE) spectra of LnCp3 (Cp = η-C5H5; Ln = Pr, Nd, Sm), measured with a wide range of photon energy, are reported.
M Corenoet al. Dalton Trans (2014).
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Selectivity in fragmentation of N-methylacetamide
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The fragmentation pattern of the peptide model system, N-methylacetamide, after resonant K-shell excitation is investigated using ion time-of-flight spectroscopy. A tendency for site-specific fragmentation, in particular preferential peptide bond cleavage occurring upon resonant excitation of N1s electrons is observed. P. Salen et al. PCCP (2014)
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The soft X-ray absorption spectrum of the allyl free radical
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HR XAS of the allyl free radical (CH2CHCH2)) was measured using a3D-ion-coincidence TOF mass spectrometer. The intense features in the spectrum could be assigned with the aid of ab initio simulation at the MCSCF level, required because of the multi-reference nature of the core-excited state wavefunctions of the open shell molecule. M. Alagia et al PCCP (2013)
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Dissociative double photoionization of benzene molecules in the 26-33 eV energy range
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A new method for the determination of dynamical features of the molecular dication dissociation processes, following the single photon double ionization, investigated by time-of-flight mass spectrometry technique has been developed.
M. Alagia et a. Chem. Phys.(2012)
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Accessing the fractal dimension of free clusters in supersonic beams
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Here a method for the quantitative determination of a morphology descriptor of free cluster with complex nanostructure is presented and applied to transition metal nanoparticles produced by a pulsed vaporization source
T. Mazza et al. New J. Phys. (2011)
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Elucitadind the 3d electronic configuration in Manganese Phthalocianine
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Core ionization of a molecule just above the 1s ionization potential leads to recapture processes where the photoelectron is pushed back to a high Rydberg orbital of the molecular ion. Upon dissociation highly excited neutral fragments can be produced together with ions.
Kivimaki A et al. Phys. Rev. A 88 (2014) 043412
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Last Updated on Thursday, 28 November 2019 11:44